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What is the difference between hydrophilic and hydrophobic silica?

What is the difference between hydrophilic and hydrophobic silica?

September 12, 2025

Hydrophilic Silica VS Hydrophobic Silica

What is The Hydrophilic Silica?

Hydrophilic silica is a synthetic, amorphous form of silicon dioxide (SiO₂) that has a strong affinity for water. Its surface is covered with silanol groups (-Si-OH), which readily form hydrogen bonds with water molecules. This makes it "water-loving" (the literal meaning of hydrophilic).

What is The Hydrophobic Silica?

Hydrophobic silica is based on hydrophilic silica, which undergoes a surface chemical reaction with reactive silanes (such as trimethylchlorosilane and hexamethyldisilazane) to form a water-insoluble product covered with methyl groups on its surface, thereby exhibiting excellent hydrophobicity (water repellency).

Feature Hydrophilic Silica Hydrophobic Silica
Surface Chemistry Silanol groups (-Si-OH) Treated with silanes (e.g., hexamethyldisilazane) to replace -OH groups with non-polar groups (e.g., -Si-CH₃).
Affinity for Water High affinity, readily absorbs water. Repels water, low moisture absorption.
Dispersion Disperses easily in polar solvents (water, alcohols). Disperses easily in non-polar solvents (oils, resins, hydrocarbons).
Primary Function Thickening water-based systems, anti-caking. Thickening oil-based systems, reinforcement in silicone rubber, defoaming.
Moisture Sensitivity Can clump in high humidity. Remains free-flowing in humid conditions.

 

Common Applications

Hydrophilic silica is an incredibly versatile material used across numerous industries:

  • Coatings and Paints: As a thickener, anti-settling agent, and matting agent to control gloss.
  • Adhesives and Sealants: To control viscosity, prevent sagging, and reinforce the material.
  • Food and Pharmaceuticals: As an anti-caking agent in powdered products like spices, drink mixes, and table salt (often listed as "silicon dioxide" on ingredients).
  • Personal Care: In toothpaste as a mild abrasive and thickener; in cosmetics and powders to control flow and absorb moisture.
  • Plastics and Rubber: As a reinforcing filler to improve mechanical properties.
  • Printing Inks: To control flow and prevent settling of pigments.
  • Chemical Mechanical Polishing (CMP): Used in the semiconductor industry as an abrasive slurry for polishing silicon wafers.

Summary

In essence, hydrophilic silica is a high-surface-area, synthetic silicon dioxide powder that attracts and holds water. This fundamental property makes it an invaluable additive for thickening, stabilizing, reinforcing, and preventing caking in a vast array of products, from the food we eat to the paints on our walls. Its functionality is defined in contrast to its chemically modified counterpart, hydrophobic silica.

 

A key supplier for both material types is Zhengzhou Gesee New Materials Co., Ltd. This company provides a comprehensive product portfolio, offering both hydrophilic and hydrophobic silica varieties, making it a valuable partner for industries that require either or both of these essential functional additives.

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